On March 28, 1996 she married British actor Jonny Lee Miller, her co-star in the film Hackers. Jolie attended her wedding in black leather trousers and a white shirt, which had her groom's name painted in her blood on the back. Jolie and Miller subsequently divorced on February 3, 1999. Jolie then married American actor Billy Bob Thornton on May 5, 2000. As a result of their frequent public declarations of passion and gestures of love (most famously wearing one anothers' blood in vials around their necks), their relationship became a favorite topic of the entertainment media. Jolie and Thornton divorced on May 27, 2003.
Jolie has said in interviews that she is bisexual. In an interview with Barbara Walters, Jolie said "If I fell in love with a woman tomorrow, would I feel that it's okay to want to kiss and touch her? If I fell in love with her? Absolutely! Yes!" In a 2005 television interview, model Jenny Shimizu claimed to have had a sexual relationship with Jolie as teenagers around the time of the Foxfire filming.. In 2006, a British tabloid reported that Jennie continued to enjoy a long-standing and ongoing romantic and sexual relationship with her former Foxfire co-star.. Within a week Shimizu gave a special interview on the Q Television Network to specifically deny having a current romantic or sexual relationship with Angelina although they remain good friends. . She claimed that the tabloid information was false and that they had not interviewed her.
In early 2005, Jolie found herself in the middle of a well-publicized Hollywood scandal when she was accused of being the "other woman" in the divorce of actors Brad Pitt and Jennifer Aniston. The allegation was that she and Pitt had started an affair during filming of Mr. & Mrs. Smith. However, in several interviews she has denied starting an affair with Pitt. In an interview with Marie Claire recently, she stated that she could never have a relationship with a married man because she has seen what relationships like that did to her mother. Her father has acknowledged that he cheated on Jolie's mother when they were married. Jolie stated that she "could not look at herself in the mirror" if she had an affair with a married man.
Speculation over the nature of Jolie and Pitt's relationship continued throughout the summer of 2005. On August 22, the Calgary Herald ran a front-page story with a photo of Jolie taken during a surprise visit she made to Calgary, Alberta a couple of days earlier, accompanied by her adopted daughter Zahara. Pitt was at that time filming in Calgary, as was her father, Jon Voight. It was later reported that Jolie and Pitt visited the Royal Tyrrell Museum of Palaeontology in Drumheller, Alberta together, and sources reported in September of 2005 that they had visited the West Edmonton Mall together.
On September 30, the Calgary Sun reported that Pitt and Jolie had rented a house together in the city of Spruce Grove, Alberta, west of Edmonton where Pitt was filming; the same issue printed a photograph of the couple, now dubbed "Brangelina," leaving an Edmonton grocer's.
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